I've put butter on microwave popcorn before and it shriveled up on me.
Microwaves are crazy.
Maybe the butter was too hot when I added it, this was years and years ago, I had that result, so I never gave it another thought.
The best popcorn I've ever had was from a case iron pot, heated with vegetable oil, and covered in melted butter (not Imperial, real butter) and salt.
I do think it has a lot to do with the way the seeds are heated though.
You should look into buying one of these, they are cool, and I still use mine I bought years ago.
http://www.amazon.com/Hand-Crank-Popcorn-Popper-Quart/dp/B000ST0WZQ
(not this exact model, mine was from a fund raiser, but this type of pan)
And if you have kids, you can involve them in turning the crank.
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