The only approved discs for BD-Video are BD25 and BD50 discs.
In order for them to use a bigger disc for movies, they'd have to ensure that it could work with all current models of Blu-ray Disc players.
There's not much reason for a disc bigger than a BD50 right now.
For PC usage it's a different matter altogether. You should start seeing BD100 and BD200 BD-R's showing up within the next year or so.